104-29-0
- Product Name：Chlorphenesin
- Molecular Formula：C9H11ClO3
- Purity：99%
- Molecular Weight：202.638
Product Details
pd_meltingpoint:77-79 °C
Appearance:white to off-white crystalline powder
Export Top Purity Chlorphenesin 104-29-0 In Stock
- Molecular Formula:C9H11ClO3
- Molecular Weight:202.638
- Appearance/Colour:white to off-white crystalline powder
- Vapor Pressure:4.13E-06mmHg at 25°C
- Melting Point:77-79 °C
- Refractive Index:1.565
- Boiling Point:369.45 °C at 760 mmHg
- PKA:13.44±0.20(Predicted)
- Flash Point:177.237 °C
- PSA：49.69000
- Density:1.318 g/cm3
- LogP:1.07200
Chlorphenesin(Cas 104-29-0) Usage
|
Definition |
ChEBI: Glycerol in which the hydrogen of one of the primary hydroxy groups is substituted by a 4-chlorophenyl group. It has antifungal and antibacterial properties, and is used for treatment of cutaneous and vaginal infections. Its 1-carbamate is used as a skelet l muscle relaxant for the treatment of painful muscle spasm. |
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Brand name |
Maolate (Pharmacia & Upjohn). |
|
Flammability and Explosibility |
Notclassified |
InChI:InChI=1/C9H11ClO3/c10-7-1-3-9(4-2-7)13-6-8(12)5-11/h1-4,8,11-12H,5-6H2/t8-/m0/s1
104-29-0 Relevant articles
A New and Efficient Heterogeneous System for the Oxidative Cleavage of 1,2-Diols and the Oxidation of Hydroquinones
Daumas, M.,Vo-Quang, Y.,Vo-Quang, L.,Goffic, F. Le
, p. 64 - 65 (1989)
Sodium periodate/wet silica gel in the p...
One-pot synthesis of aryloxypropanediols from glycerol: Towards valuable chemicals from renewable sources
Truscello, Ada M.,Gambarotti, Cristian,Lauria, Mirvana,Auricchio, Sergio,Leonardi, Gabriella,Shisodia, Suresh U.,Citterio, Attilio
, p. 625 - 628 (2013)
Glycerol offers an easy and green route ...
Kinetics and mechanism of degradation of chlorphenesin carbamate in strongly acidic aqueous solutions
Hara,Hayashi,Yoshida
, p. 3481 - 3484 (1986)
-
Ligand-Free Copper-Catalyzed Ullmann-Type C?O Bond Formation in Non-Innocent Deep Eutectic Solvents under Aerobic Conditions
Capriati, Vito,García-álvarez, Joaquín,Marinò, Manuela,Perna, Filippo M.,Quivelli, Andrea Francesca,Vitale, Paola
, (2021/12/09)
An efficient and novel protocol was deve...
Exploration of the expeditious potential of Pseudomonas fluorescens lipase in the kinetic resolution of racemic intermediates and its validation through molecular docking
Soni, Surbhi,Dwivedee, Bharat P.,Sharma, Vishnu K.,Patel, Gopal,Banerjee, Uttam C.
, p. 85 - 94 (2017/12/26)
A profoundly time-efficient chemoenzymat...
Method for green, efficient and selective synthesis of chlorphenesin
-
Paragraph 0028-0043, (2018/09/13)
The invention discloses a method for gre...
A synthesis method of chlorphenesin
-
Paragraph 0082; 0083, (2017/09/01)
The invention relates to a synthetic met...
104-29-0 Process route
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- 61514-96-3
3-(p-chlorophenoxy)-1,2-propanediol-2-carbamate
-
- 886-74-8,126632-50-6
chlorphenesin carbamate
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- 104-29-0
chlorphenesin
| Conditions | Yield |
|---|---|
|
With sodium hydroxide; In water; at 0 ℃; Rate constant; degradation was studied;
|
-
- 106-48-9,82344-39-6
4-chloro-phenol
-
- 96-24-2
3-monochloro-1,2-propanediol
-
- 104-29-0
chlorphenesin
| Conditions | Yield |
|---|---|
|
With tetrabutylammomium bromide; sodium hydroxide; at 105 ℃; for 3h; Concentration; Reagent/catalyst;
|
95.1% |
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With sodium hydroxide; In ethanol; for 2h; Heating;
|
81% |
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With alkali;
|
|
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With sodium ethanolate;
|
|
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With potassium carbonate; Yield given. Multistep reaction; 1.) CH3CN, reflux, 1 h, 2.) reflux, overnight;
|
|
|
With potassium carbonate; Yield given. Multistep reaction; 1.) acetonitrile, reflux, 1 h, 2.) reflux, overnight;
|
104-29-0 Upstream products
-
106-48-9
4-chloro-phenol
-
96-24-2
3-monochloro-1,2-propanediol
-
62067-19-0
2-Benzyloxy-3-(4-chloro-phenoxy)-propan-1-ol
-
2212-05-7
4-chlorophenyl 2,3-epoxypropyl ether
104-29-0 Downstream products
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39735-79-0
1-chloro-3-(4-chloro-phenoxy)-propan-2-ol
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43018-72-0
p-chlorophenoxyacetaldehyde
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23958-75-0
Chloro-acetic acid 3-(4-chloro-phenoxy)-2-hydroxy-propyl ester
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23958-86-3
Chloro-acetic acid 1-(2-chloro-acetoxymethyl)-2-(4-chloro-phenoxy)-ethyl ester
Relevant Products
-
Sodium PolyglutamateCAS：25513-46-6
-
N-Acetylneuraminic AcidCAS：131-48-6
-
Piroctone OlamineCAS：68890-66-4
